Hellmann–Feynman theorem
Theorem that relates the derivative of the total energy with respect to a parameter, to the expectation value of the derivative of the Hamiltonian with respect to that same parameter
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- Defining formula
\frac{\mathrm dE_\lambda}{\mathrm d\lambda}=\left\langle\psi_\lambda\left|\frac{\mathrm d\hat H_\lambda}{\mathrm d\lambda}\right|\psi_\lambda\right\rangle
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